Publication: A germanium(II)-centered dication
All || By Area || By Year| Title | A germanium(II)-centered dication | Authors/Editors* | P. A. Rupar, V. N. Staroverov, P. J. Ragogna, and K. M. Baines, |
|---|---|
| Where published* | J. Am. Chem. Soc. |
| How published* | Journal |
| Year* | 2007 |
| Volume | 129 |
| Number | 49 |
| Pages | 15138-15139 |
| Publisher | American Chemical Society |
| Keywords | electronic structure calculations, population analysis |
| Link | http://pubs.acs.org/doi/abs/10.1021/ja0775725 |
| Abstract |
The dicationic 4(2+) complex with three N-heterocyclic carbenes coordinated to a germanium center is reported. The complex was characterized by 1H NMR and FT Raman spectroscopy, and the structure was determined by single-crystal X-ray diffraction. Electronic structure calculations reveal a partial positive charge at germanium and that the germanium lone pair shows no evidence for bonding. |
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