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Publication: Epitaxially Driven Formation of Intricate Supported Gold Nanostructures on a Lattice-Matched Oxide Substrate

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Title Epitaxially Driven Formation of Intricate Supported Gold Nanostructures on a Lattice-Matched Oxide Substrate
Authors/Editors* G A Devenyi, J F Li, R A, Hughs, A-C Shi, P Mascher, J S, Preston
Where published* Nano Letters
How published* Journal
Year* 2009
Volume 12
Number
Pages 4258-4263
Publisher
Keywords
Link http://pubs.acs.org/doi/abs/10.1021/nl902491g
Abstract
A new class of gold nanostructures has been fabricated on the (100), (111), and (110) surfaces of lattice-matched MgAl2O4 substrates. The nanostructures were fabricated through a synthesis route where a thin gold film dewets, liquefies, and then slowly self-assembles. The supported nanostructures are intricately shaped, crystalline, and epitaxially aligned. Simulations based on a continuum elastic theory indicate that the self-assembly is driven by strained epitaxy and minimization of the surface free energy.

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